Silver Catalyzed Oxidation of Ethylene
نویسندگان
چکیده
منابع مشابه
Oxidation of Ethylene to Ethylene Oxide by Selenium Modified Silver Catalyst
Oxidation of ethylene to ethylene oxide over silver catalyst and selenium modified catalyst has been studied by continuous flow and pulse techniques over the temperature range of 230-280 °C. The results are discussed in terms of reaction mechanisms proposed by others, rejecting mechanisms which involve peroxide formation. It has been shown that not only selectivity towards ethylene oxide pr...
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We report on theoretical and experimental studies of the reactivity of ethylene with oxygen in two well-known oxygen induced surface reconstructions on silver, the p(2 × 1) reconstruction on the Ag(110) surface and the p(4 × 4) reconstruction on the Ag(111) surface. Density functional theory calculations demonstrate that ethylene can react with oxygen on both surfaces to form an oxametallacycle...
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oxidation of ethylene to ethylene oxide over silver catalyst and selenium modified catalyst has been studied by continuous flow and pulse techniques over the temperature range of 230-280 °c. the results are discussed in terms of reaction mechanisms proposed by others, rejecting mechanisms which involve peroxide formation. it has been shown that not only selectivity towards ethylene oxide produc...
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Ethylene was oxidatively dehydrogenated by the adsorbed oxygen atoms to surface hydroxide and surface carbon atoms. The surface hydroxide intermediates rapidly reacted to yield water and adsorbed atomic oxygen, and the carbon atoms were subsequently oxidized by the oxygen atoms to carbon dioxide. The combustion of surface carbon, reaction step (3), only occurred at temperatures exceeding -400 K...
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The mechanism of the CO oxidation promoted by a neutral Ag(55) cluster was investigated extensively, using density functional theory calculations. The CO oxidation process catalyzed by anionic and cationic Ag(55) clusters was also studied, to clarify the effects of the charge state. The Eley-Rideal (ER) and Langmuir-Hinshelwood (LH) mechanisms were discussed in detail. Six reaction pathways wer...
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ژورنال
عنوان ژورنال: Journal of Synthetic Organic Chemistry, Japan
سال: 1959
ISSN: 0037-9980,1883-6526
DOI: 10.5059/yukigoseikyokaishi.17.564